A copper-catalyzed phosphorylation–peroxidation of alkenes has been developed. The three-component protocol provides practical access to multisubstituted β-phosphoryl peroxides by the reactions of P(O)–H compounds, alkenes and tert-butyl hydroperoxide (TBHP). The obtained β-phosphoryl peroxides can be applied to the synthesis of β-phosphoryl epoxides by using lithium bis(trimethylsilyl)amide (LHMDS) as a base.

中文翻译：

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铜催化的烯烃三组分磷酸化-过氧化†

已经开发出铜催化的烯烃的磷酸化-过氧化反应。三组分方案通过P（O）–H化合物，烯烃和叔丁基氢过氧化物（TBHP）的反应提供了多取代的β-磷酰过氧化物的实用途径。以双（三甲基甲硅烷基）酰胺锂（LHMDS）为基础，可以将所得的β-磷酰基过氧化物用于合成β-磷酰基环氧化物。