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Synthesis, Characterization, and Antimicrobial Activity of RhIII and IrIII β-Diketonato Piano-Stool Compounds
Organometallics ( IF 2.8 ) Pub Date : 2017-12-20 00:00:00 , DOI: 10.1021/acs.organomet.7b00742
Christine M. DuChane 1 , Loren C. Brown 1 , Virginia S. Dozier 1 , Joseph S. Merola 1
Affiliation  

A series of RhIII and IrIII half-sandwich compounds of the type [(η5-Cp*R)M(β-diketonato)Cl] were synthesized and characterized, including 17 X-ray crystallographic structures. In general, the complexes were synthesized in short reaction times and in good yield. The antimicrobial properties of these complexes were tested against a variety of microbes, and several complexes were found to have good activity against Mycobacterium smegmatis.

中文翻译:

合成,表征,和Rh的抗菌活性III和Ir III β-二酮盐钢琴凳化合物

一系列的Rh的III和Ir III的类型的半夹心化合物[(η 5 -Cp * - [R)M(β-二酮盐)CL]被合成和表征,其中包括17 X射线晶体结构。通常,以短的反应时间和良好的产率合成配合物。测试了这些复合物对多种微生物的抗菌性能,发现几种复合物对耻垢分枝杆菌具有良好的活性。
更新日期:2017-12-21
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