Efficient visible light-driven water oxidation catalysts based on B-β-{BiW8O30} and unique 14-nuclear hetero-metal sandwich unit,Chemical Communications

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Efficient visible light-driven water oxidation catalysts based on B-β-{BiW8O30} and unique 14-nuclear hetero-metal sandwich unit
Chemical Communications ( IF 4.9 ) Pub Date : 2017-12-20 00:00:00 , DOI: 10.1039/c7cc06064e
Lige Gong _{1,

2,

3,

4,

5} , Li Yu _{5,

6,

7} , Kai Yu _{1,

2,

3,

4,

5} , Yong Ding _{5,

6,

7} , Jinhua Lv _{1,

2,

3,

4,

5} , Chunmei Wang _{1,

2,

3,

4,

5} , Zhanhua Su _{1,

2,

3,

4,

5} , Baibin Zhou _{1,

2,

3,

4,

5}

Affiliation

A sandwich tungstobismuthate with new topology based on {B-β-BiW₈O₃₀}-cluster and unique 14-nuclear sandwich unit is reported as a high-efficiency visible light-driven water oxidation catalyst containing extended hetero-metal oxygen layer. At optimal conditions, the turn-over number (TON) of the title compound can reach 205.5 with O₂ yield of 32.88%.

中文翻译：

基于B-β-{BiW ₈ O ₃₀ }和独特的14核异金属夹心单元的高效可见光驱动水氧化催化剂

夹心tungstobismuthate基于{B-β-白车身新拓扑₈ ö ₃₀ } -cluster和独特的14核夹心单元报告为含有扩展异质金属氧层的高效率可见光驱动的水氧化的催化剂。在最佳条件下，标题化合物的周转数（TON）可以达到205.5，O ₂产率为32.88％。

更新日期：2018-01-16

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