Nowadays, energy generation and storage are two important topics. Unfortunately, conventional energy generators are not capable of responding to environmental changes, while traditional energy storage devices lack special functionalities apart from supplying electricity. Benefiting from exceptional physicochemical properties, graphene-based materials help to address the aforementioned issues. In this review, we highlight recent key advances in graphene-based smart energy generation and storage systems. In terms of smart energy generation, we focus on graphene-derived electric generators that can controllably produce electricity in response to external stimuli, such as moisture, flowing liquid, friction, pressure force, and heat. As for energy storage, smart batteries and supercapacitors with made-to-measure graphene materials are summarized to show impressive features of deformability, wearability, printability, stimuli response, self-healing, integration, and miniaturization. Beyond these, we also discuss the challenges ahead for these graphene-related smart energy generation/storage devices and their future development trend.

如今，能源的产生和存储是两个重要的主题。不幸的是，传统的能量产生器不能对环境变化做出反应，而传统的能量存储设备除了供电以外还缺乏特殊的功能。得益于出色的理化特性，基于石墨烯的材料有助于解决上述问题。在本文中，我们重点介绍了基于石墨烯的智能能源发电和存储系统的最新关键进展。在智能能源发电方面，我们专注于石墨烯发电机，这些发电机可以响应外部刺激（如水分，流动的液体，摩擦，压力和热量）可控地发电。至于储能 总结了采用量身定制的石墨烯材料的智能电池和超级电容器，它们显示出令人印象深刻的可变形性，耐磨性，可印刷性，刺激响应，自愈，集成和小型化的特征。除此之外，我们还将讨论与这些石墨烯相关的智能能源发电/存储设备所面临的挑战及其未来的发展趋势。