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Organic-free synthesis and ortho-reaction of monodisperse Ni incorporated CeO2 nanocatalysts†
Journal of Materials Chemistry A ( IF 11.9 ) Pub Date : 2017-12-18 00:00:00 , DOI: 10.1039/c7ta08872h
W. L. Wang 1, 2, 3, 4, 5 , W. Y. Liu 1, 2, 3, 4, 5 , X. L. Weng 1, 2, 3, 4, 5 , Y. Shang 1, 2, 3, 4, 5 , J. J. Chen 1, 2, 3, 4, 5 , Z. G. Chen 1, 2, 3, 4, 5 , Z. B. Wu 1, 2, 3, 4, 5
Affiliation  

We explore an organic-free route for the synthesis of monodisperse Ni incorporated CeO2 nanocatalysts, which show enriched oxygen vacancies and high redox potentials. In particular, we unveil an ortho-reaction mechanism of the catalyst, which can ensure sufficient contact and reaction of adsorbents and might be very beneficial to Langmuir–Hinshelwood type reactions.

中文翻译:

单分散掺Ni的CeO 2纳米催化剂的无有机合成和邻位反应

我们探索了无有机合成单分散掺Ni的CeO 2纳米催化剂的方法,该方法显示出富集的氧空位和高氧化还原电势。特别是,我们揭示了催化剂的邻位反应机理,该机理可以确保吸附剂充分接触和反应,并且可能对Langmuir-Hinshelwood型反应非常有益。
更新日期:2017-12-18
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