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Fabrication and spectral properties of Dy: Y2O3 transparent ceramics
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2017-12-15 , DOI: 10.1016/j.jeurceramsoc.2017.12.020
Zongwen Hu , Xiaodong Xu , Jun Wang , Peng Liu , Dongzhen Li , Xiaodan Wang , Jian Zhang , Jun Xu , Dingyuan Tang

Dy3+-doped Y2O3 ceramics were fabricated by Spark Plasma Sintering method. The effect of sintering temperature on the microstructure and the optical transmittance of the ceramics was studied. The maximum in-line transmittance of Dy:Y2O3 ceramics with thickness of 1 mm was 74.5% at 574 nm when sintering temperature was 1550 ℃. The spectroscopic parameters were determined by Judd-Ofelt theory based on the room temperature absorption spectra. The peak emission cross section for the 4F9/26H13/2 transition was calculated to be 0.569×10-20 cm2. The fluorescence decay curve and quantum efficiency of the 4F9/2 multiplet were measured to be 269.2 µs and 37.1%, respectively.



中文翻译:

Dy:Y 2 O 3透明陶瓷的制备及光谱性质

通过等离子烧结法制备了Dy 3+掺杂的Y 2 O 3陶瓷。研究了烧结温度对陶瓷显微组织和透光率的影响。烧结温度为1550℃时,厚度为1 mm的Dy:Y 2 O 3陶瓷在574 nm下的最大在线透射率为74.5%。根据室温吸收光谱,通过Judd-Ofelt理论确定光谱参数。为峰值发射的横截面4 ˚F 9/26 ħ 13/2过渡计算为0.569×10 -20厘米2。经测定,4 F 9/2多重的荧光衰减曲线和量子效率分别为269.2 µs和37.1%。

更新日期:2017-12-16
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