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Electrocatalytic activity of CoFe2O4 thin films prepared by AACVD towards the oxygen evolution reaction in alkaline media
Electrochemistry Communications ( IF 5.4 ) Pub Date : 2017-12-15 , DOI: 10.1016/j.elecom.2017.12.017
Jagdeep S. Sagu , Diana Mehta , K.G. Upul Wijayantha

The electrocatalytic behaviour of CoFe2O4 thin films, prepared by aerosol-assisted chemical vapour deposition, towards the oxygen evolution reaction in an alkaline medium is reported. X-ray diffraction and SEM data show that the CoFe2O4 thin films are phase pure and consist of dendrites 0.5–1 μm in diameter rising from the surface with heights ranging from 1 to 3 μm. The CoFe2O4 thin films exhibited an overpotential of 490 mV at a current density of 10 mA cm− 2, and a Tafel slope of 54.2 mV dec− 1. Taking into account the electrochemically active surface area, the intrinsic activity of CoFe2O4 was found to be 1.75 mA cm− 2real at an overpotential of 490 mV. The CoFe2O4 thin films were highly stable and were capable of maintaining catalytic activity for at least 12 h.



中文翻译:

AACVD法制备的CoFe 2 O 4薄膜对碱性介质中氧释放反应的电催化活性

报道了通过气溶胶辅助化学气相沉积制备的CoFe 2 O 4薄膜在碱性介质中对氧释放反应的电催化行为。X射线衍射和SEM数据表明,CoFe 2 O 4薄膜是相纯的,由直径从0.5到1μm的树枝状晶体组成,其表面高度从1到3μm不等。CoFe 2 O 4薄膜在10 mA cm -2的电流密度下表现出490 mV的过电势,并且Tafel斜率为54.2 mV dec -1。考虑到电化学活性表面积,CoFe 2 O 4的固有活性发现在490 mV的超电势下为1.75 mA cm -2实数。CoFe 2 O 4薄膜具有很高的稳定性,并能够保持至少12小时的催化活性。

更新日期:2017-12-15
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