当前位置: X-MOL 学术Micropor. Mesopor. Mater. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Atom economical benzylation of phenol with benzyl alcohol using 20 % (w/w)Cs2.5H0.5PW12O40 supported on mesocellular foam silica (MCF) and its kinetics
Microporous and Mesoporous Materials ( IF 5.2 ) Pub Date : 2017-12-15 , DOI: 10.1016/j.micromeso.2017.12.017
Kalpesh H. Bhadra , Ganapati D. Yadav

Traditionally benzylation of phenol is carried out with benzyl chloride which is corrosive and difficult to handle, and the resultant reaction is not atom economical. Benzyl alcohol is an alternative to benzyl chloride which is safe and easy to handle. Benzyl phenols are industrially important products particularly in plastic, rubber and petroleum industries. In present study, cesium salt of dodecatungstophosphoric acid (Cs2.5H0.5PW12O40, Cs-DTP) supported on mesocellular foam (MCF) silica was used as catalyst among others. The activity of prepared catalyst, 20% (w/w) Cs-DTP/MCF was compared with Amberlyst-15, montmorillonite clay K10, S-ZrO2 and unsupported Cs-DTP catalyst. The supported catalyst showed better performance because of even distribution of acidic sites on MCF. The effect of reaction parameters were studied in detail and it was found that reaction follows second order kinetics. The activation energy was found to be 15.94 kcal/mol. The catalyst was found reusable.



中文翻译:

介孔泡沫二氧化硅(MCF)负载20%(w / w)Cs 2.5 H 0.5 PW 12 O 40的苯甲醇与苯甲醇的原子经济苄化反应及其动力学。

传统上,苯酚的苄基化是用苄基氯进行的,该苄基氯具有腐蚀性且难以处理,并且所得反应在原子上也不经济。苄醇是安全且易于处理的苄基氯的替代物。苄基酚是工业上重要的产品,特别是在塑料,橡胶和石油工业中。在本研究中,十二烷基磷酸二氢铯盐(Cs 2.5 H 0.5 PW 12 O 40,Cs-DTP)负载在介孔泡沫(MCF)二氧化硅上用作催化剂。将制备的催化剂20%(w / w)Cs-DTP / MCF的活性与Amberlyst-15,蒙脱土K10,S-ZrO 2进行比较和不支持的Cs-DTP催化剂。负载的催化剂表现出更好的性能,因为酸性位在MCF上均匀分布。详细研究了反应参数的影响,发现反应遵循二级动力学。发现活化能为15.94kcal / mol。发现该催化剂可重复使用。

更新日期:2017-12-15
down
wechat
bug