In this issue of Chem, Liu and co-workers report an extremely general and mild radical diamination protocol that permits the asymmetric synthesis of vicinal diamines in a highly enantioselective manner under a copper(I)/chiral phosphate dual-catalytic system. Notably, this work represents the first asymmetric radical alkene diamination that allows for direct alkylamine incorporation.

中文翻译：

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去除烯烃催化不对称胺化反应中的掩模

在本期《化学》杂志上，Liu和他的同事报告了一种极其通用和温和的自由基正电子化方案，该方案允许在铜（I）/手性磷酸酯双催化体系下以高对映选择性的方式不对称合成邻位二胺。值得注意的是，该工作代表了允许烷基胺直接引入的第一个不对称自由基烯键化。