Abstract

This report highlights the recent advances for glycerol valorization to valuable products in liquid phase continuous flow systems using different types of catalysts and processes. The main biobased chemicals obtained from glycerol, such as acrolein, lactic acid, dihydroxyacetone, propanediols, glycerol carbonate, solketal, acetin, alkyl ethers, and oligomers, will be presented.

1 Introduction

2 Continuous Dehydration

2.1 Without Added Catalyst

2.2 With Acid Catalyst

3 Continuous Oxidation

4 Continuous Hydrogenolysis

5 Continuous Carbonatation

6 Continuous Ketalization

7 Continuous Esterification

8 Continuous Etherification

9 Continuous Oligomerization

10 Outlook

11 Conclusion

This report highlights the recent advances for glycerol valorization to valuable products in liquid phase continuous flow systems using different types of catalysts and processes. The main biobased chemicals obtained from glycerol, such as acrolein, lactic acid, dihydroxyacetone, propanediols, glycerol carbonate, solketal, acetin, alkyl ethers, and oligomers, will be presented.

1 Introduction

2 Continuous Dehydration

2.1 Without Added Catalyst

2.2 With Acid Catalyst

3 Continuous Oxidation

4 Continuous Hydrogenolysis

5 Continuous Carbonatation

6 Continuous Ketalization

7 Continuous Esterification

8 Continuous Etherification

9 Continuous Oligomerization

10 Outlook

11 Conclusion

中文翻译：

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甘油到化学品的连续流转化：概述

摘要

本报告重点介绍了使用不同类型的催化剂和工艺在液相连续流系统中将甘油增值成有价值的产品的最新进展。将介绍从甘油获得的主要生物基化学品，例如丙烯醛，乳酸，二羟基丙酮，丙二醇，碳酸甘油酯，Solketal，丙酮，烷基醚和低聚物。

1引言

2连续脱水

2.1不添加催化剂

2.2用酸催化剂

3连续氧化

4连续氢解

5连续碳化

6连续化

7连续酯化

8连续醚化

9连续低聚

10展望

11结论

本报告重点介绍了使用不同类型的催化剂和工艺在液相连续流系统中将甘油增值成有价值的产品的最新进展。将介绍从甘油获得的主要生物基化学品，例如丙烯醛，乳酸，二羟基丙酮，丙二醇，碳酸甘油酯，Solketal，丙酮，烷基醚和低聚物。

1引言

2连续脱水

2.1不添加催化剂

2.2用酸催化剂

3连续氧化

4连续氢解

5连续碳化

6连续化

7连续酯化

8连续醚化

9连续低聚

10展望

11结论