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Recent Advances in Nickel Catalysis Enabled by Stoichiometric Metallic Reducing Agents
Synthesis ( IF 2.6 ) Pub Date : 2017-12-14 , DOI: 10.1055/s-0036-1591853
Edward Richmond , Joseph Moran

Abstract

This short review describes recent advances in the field of nickel catalysis, specifically transformations employing stable Ni(II) precatalysts that are activated in situ with the use of stoichiometric metallic reducing agents. The article seeks to summarise the field, highlighting key studies and discussing mechanistic facets. The review closes with an eye on future directions in redox-enabled nickel catalysis.

1 Introduction

2 Nickel Catalysis Enabled by Metallic Reducing Agents

3 Reductive Cross-Coupling

4 Reductive Carboxylation and Acylation-type reactions

5 Miscellaneous Reactivity

6 Perspectives and Future Directions

This short review describes recent advances in the field of nickel catalysis, specifically transformations employing stable Ni(II) precatalysts that are activated in situ with the use of stoichiometric metallic reducing agents. The article seeks to summarise the field, highlighting key studies and discussing mechanistic facets. The review closes with an eye on future directions in redox-enabled nickel catalysis.

1 Introduction

2 Nickel Catalysis Enabled by Metallic Reducing Agents

3 Reductive Cross-Coupling

4 Reductive Carboxylation and Acylation-type reactions

5 Miscellaneous Reactivity

6 Perspectives and Future Directions



中文翻译:

化学计量金属还原剂在镍催化中的最新进展

摘要

这篇简短的评论介绍了镍催化领域的最新进展,特别是使用稳定的Ni(II)预催化剂进行的转化,该催化剂通过化学计量的金属还原剂就地活化。本文旨在总结该领域,突出重点研究并讨论机械方面。本文以氧化还原活化镍催化的未来方向为结尾。

1引言

2金属还原剂对镍的催化作用

3还原交叉耦合

4还原性羧化和酰化型反应

5其他反应

6观点和未来方向

这篇简短的评论介绍了镍催化领域的最新进展,特别是使用稳定的Ni(II)预催化剂进行的转化,该催化剂通过化学计量的金属还原剂就地活化。本文旨在总结该领域,突出重点研究并讨论机械方面。本文以氧化还原活化镍催化的未来方向为结尾。

1引言

2金属还原剂对镍的催化作用

3还原交叉耦合

4还原性羧化和酰化型反应

5其他反应

6观点和未来方向

更新日期:2017-12-14
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