We previously proposed (Gourdin-Bertin, S. and Chassagne, C. J. Chem. Phys. 2016, 144 (24)) a simple theoretical model to account for the evolution of conductivity with dielectric permittivity in nonpolar media. In this article, we validate the theory experimentally for the case of an ionogenic species kept at a constant chemical potential (i.e., in equilibrium with a nondissolved salt, in contrast to previously published conductivity measurements carried out as a function of various fully dissolved salt concentrations). To our knowledge, it is the first time that this type of experiment has been performed explicitly.

中文翻译：

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经典热力学在非极性介质电导率中的应用：实验验证

我们以前曾建议（Gourdin-Bertin，S.和Chassagne，C. J.化学。物理 2016，144（24））的简单的理论模型以考虑导电性与非极性介质介电常数的演变。在本文中，我们针对具有恒定化学势（即与非溶解盐保持平衡）的电离物种进行实验验证了该理论，这与先前公布的电导率测量结果不同，该电导率测量是各种完全溶解盐浓度的函数）。据我们所知，这是第一次明确进行这种类型的实验。