The present report describes two series of new porphyrazine macrocycles derived from tetrakis(selenodiazole)porphyrazine, TSeDPzH 2, having the formulae [ TSeDPzM ]( CH 3 COOH )( H 2 O )x M = Mn (II), Co (II), Ni (II), Zn (II); x = 4–6) and [ TSeDPzM ( py )]( CH 3 COOH )( H 2 O )x ( M = Mn (II), Co (II), Ni (II); x = 1–5), obtained by reaction of the free ligand with the appropriate metal acetate in dimethyl (DMSO), and, respectively, pyridine. All the species isolated are stable-to-air substantially amorphous materials, almost completely insoluble in the usual organic solvents and N -donors (pyridine etc.), and only slightly soluble in CF3COOH or 96% H 2 SO 4. The complexes have been investigated by IR, Raman, and UV-vis spectra, and magnetic susceptibility measurements. Their properties in terms of electronic structure and reactivity towards N -bases are discussed in comparison with their S-containing analogs and the class of the structurally similar metal phthalocyanines.

中文翻译：

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四（硒二唑）卟啉。2：与 Mn(II)、Co(II)、Ni(II) 和 Zn(II) 的金属络合物

本报告描述了从四（硒二唑）四氮杂卟啉 TSeDPzH 衍生的两个系列新的四氮杂卟啉大环化合物2, 有公式 [ TSeDPzM ]( CH3醇 )( H2○）XM = Mn(II)、Co(II)、Ni(II)、Zn(II)；x = 4–6) 和 [TSeDPzM ( py )]( CH3醇 )( H2○）X(M = Mn (II), Co (II), Ni (II); x = 1-5)，通过游离配体与合适的金属乙酸盐在二甲基 (DMSO) 和吡啶中的反应获得。所有分离的物质都是对空气稳定的基本无定形材料，几乎完全不溶于常用有机溶剂和 N 供体（吡啶等），仅微溶于 CF3COOH 或 96% H2所以4. 已经通过红外、拉曼和紫外-可见光谱以及磁化率测量对配合物进行了研究。与它们的含硫类似物和结构相似的金属酞菁类相比，讨论了它们在电子结构和对 N 碱基反应性方面的性质。