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Sulfurative self-condensation of ketones and elemental sulfur: a three-component access to thiophenes catalyzed by aniline acid–base conjugate pairs
Green Chemistry ( IF 9.8 ) Pub Date : 2017-12-13 00:00:00 , DOI: 10.1039/c7gc03437g
Thanh Binh Nguyen 1, 2, 3, 4, 5 , Pascal Retailleau 1, 2, 3, 4, 5
Affiliation  

A sulfurative self-condensation method for constructing thiophenes 2 by a reaction between ketones 1 and elemental sulfur is reported. This reaction, which is catalyzed by anilines and their salts with strong acids, starts from readily available and inexpensive materials, and releases only water as a by-product.

中文翻译:

酮和元素硫的硫化自缩合:苯胺酸-碱共轭对催化的噻吩三组分进入

报道了一种通过酮1与元素硫之间的反应来构建噻吩2的硫酸化自缩合方法。该反应由苯胺及其盐与强酸催化,从容易获得且廉价的材料开始,仅释放水作为副产物。
更新日期:2018-01-22
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