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In-situ synthesis of Cu2O/reduced graphene oxide composite as effective catalyst for ozone decomposition
Catalysis Communications ( IF 3.7 ) Pub Date : 2017-12-07 , DOI: 10.1016/j.catcom.2017.12.003
Shuyan Gong , Jiayuan Chen , Xiaofeng Wu , Ning Han , Yunfa Chen

Nowadays, highly efficient decomposition of ozone is still technologically challenging, especially in the presence of high humidity levels. In this study, Cu2O/reduced graphene oxide composite (Cu2O/rGO) is in-situ synthesized by reducing a mixed solution of Cu2 + and GO. This developed catalytic system exhibits 100% ozone (20 ppm O3/air) decomposition efficiency at room temperature with high stability. Importantly, the ozone conversion could be still above 96% at high relative humidity levels (ca. 90%) after 10 h of continuous operation. The excellent performance is suggested to be attributed to the highly active ultrafine Cu2O nanoparticles heterogeneously nucleated on rGO, which facilitate necessary electron density by the transfer of it between Cu2O and rGO phases.



中文翻译:

原位合成Cu 2 O /还原氧化石墨烯复合物作为臭氧分解的有效催化剂

如今,臭氧的高效分解仍在技术上具有挑战性,特别是在高湿度条件下。在这项研究中,铜2 O /还原的石墨烯氧化物复合物(CU 2 O / RGO)是原位通过减少铜的混合溶液中合成的2 +和GO。这种发达的催化系统在室温下具有高稳定性的100%臭氧(20 ppm O 3 /空气)分解效率。重要的是,连续运行10小时后,在高相对湿度(约90%)下,臭氧转化率仍可能高于96%。建议将优异的性能归因于高活性超细Cu 2O纳米颗粒在rGO上异质成核,通过在Cu 2 O和rGO相之间转移,可以促进必要的电子密度。

更新日期:2017-12-07
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