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DMSO modified PEDOT:PSS polymer/ZnO nanorods Schottky junction ultraviolet photodetector: Photoresponse, external quantum efficiency, detectivity, and responsivity augmentation using N doped graphene quantum dots
Organic Electronics ( IF 3.2 ) Pub Date : 2017-11-22 , DOI: 10.1016/j.orgel.2017.11.024
Saurab Dhar , Tanmoy Majumder , Pinak Chakraborty , Suvra Prakash Mondal

Schottky junction ultraviolet (UV) photodetector was fabricated by spin coating a hole conducting polymer, poly 3,4-ethylenedioxythiophene: polystyrene sulfonate (PEDOT:PSS) on hydrothermally grown zinc oxide (ZnO) nanorod array. The photodetector performance was improved by increasing the conductivity of PEDOT:PSS polymer using dimethyl sulfoxide (DMSO) additive. The UV detector performance was further enhanced significantly by sensitizing ZnO nanorods with N doped graphene quantum dots (NGQDs). NGQD decorated ZnO NRs/DMSO-PEDOT:PSS Schottky junction device demonstrated superior external quantum efficiency (EQE ∼ 90063%), responsivity (Rλ∼247 A/W) and detectivity (Dλ∼2.42 × 1011 Hz1/2/W) at 340 nm wavelength and –1V external bias. The EQE of NGQD modified sample was 56 times higher than pristine PEDOT:PSS/ZnO NR and 4.3 times higher than DMSO modified PEDOT:PSS/ZnO NRs device. NGQD sensitized detector showed superior photocurrent of 80.77 mA/cm2 at 340 nm wavelength, –1V external bias, which was 2 times higher than DMSO modified and 32 times higher than pristine PEDOT:PSS based device. The photocurrent rise and decay time of NGQD sensitized NRs are very fast compared to other photodetectors.



中文翻译:

DMSO修饰的PEDOT:PSS聚合物/ ZnO纳米棒肖特基结紫外光电探测器:使用N掺杂石墨烯量子点的光响应,外部量子效率,探测性和响应性增强

肖特基结紫外(UV)光电探测器是通过在水热生长的氧化锌(ZnO)纳米棒阵列上旋涂导电聚合物,聚3,4-乙撑二氧噻吩:聚苯乙烯磺酸盐(PEDOT:PSS)制成的。通过使用二甲基亚砜(DMSO)添加剂提高PEDOT:PSS聚合物的电导率,可以提高光电探测器的性能。通过使用N掺杂的石墨烯量子点(NGQD)敏化ZnO纳米棒,可进一步显着提高UV检测器的性能。NGQD装饰的ZnO NRs / DMSO-PEDOT:PSS肖特基结器件显示出优异的外部量子效率(EQE〜90063%),响应度([Rλ约247 A / W)和探测率(dλ在340 nm波长和–1V外部偏置下约为2.42×10 11  Hz 1/2 / W)。NGQD改性样品的EQE较原始PEDOT:PSS / ZnO NRs高56倍,比DMSO改性PEDOT:PSS / ZnO NRs装置高4.3倍。NGQD敏化检测器在340 nm波长下显示出80.77 mA / cm 2的优异光电流,–1V外部偏置,这比DMSO改性的器件高2倍,比基于PEDOT:PSS的原始器件高32倍。与其他光电探测器相比,NGQD敏化NR的光电流上升和衰减时间非常快。

更新日期:2017-11-22
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