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Homologous Co3O4‖CoP nanowires grown on carbon cloth as a high-performance electrode pair for triclosan degradation and hydrogen evolution†
Materials Chemistry Frontiers ( IF 7 ) Pub Date : 2017-12-11 00:00:00 , DOI: 10.1039/c7qm00533d
Chaojie Lyu 1, 2, 3, 4 , Jinlong Zheng 1, 2, 3, 4 , Rui Zhang 1, 2, 3, 4 , Ruqiang Zou 5, 6, 7, 8, 9 , Bin Liu 4, 7, 8, 9, 10 , Wei Zhou 1, 2, 3, 4
Affiliation  

As a widely used antimicrobial agent in toothpastes and body washes for decades, triclosan (TCS) is causing great harm to the environment through wastewater. Herein, we used a two-electrode system to remove TCS comprising Co3O4 nanowires/carbon cloth (Co3O4 NWs/CC) as anode and CoP nanowires/carbon cloth (CoP NWs/CC) as cathode. At a constant current density of 10 mA cm−2, the degradation efficiency for TCS is 95% in 60 min and it is transformed into important chemical raw materials, including phenol, 1,2-dihydroxybenzene, and 2-phenoxyphenol. Subsequently, hydrogen is generated on the CoP NWs/CC cathode with Faradaic efficiency of nearly 100%. The synergetic effect of the superhydrophilic surfaces of the Co3O4 NWs/CC anode and the CoP NWs/CC cathode as well as the superaerophobicity of the cathode assures full contact of the electrolyte solution and the active materials and high-efficiency generation of H2 bubbles.

中文翻译:

同源钴3 ö 4个‖CoP纳米线生长在碳布作为一种高性能电极对三氯生退化和析氢

作为数十年来在牙膏和沐浴露中广泛使用的抗菌剂,三氯生(TCS)通过废水对环境造成了极大的伤害。在这里,我们使用两电极系统去除TCS,其中包括Co 3 O 4纳米线/碳布(Co 3 O 4 NWs / CC)作为阳极,CoP纳米线/碳布(CoP NWs / CC)作为阴极。在10 mA cm -2的恒定电流密度下,TCS的降解效率在60分钟内达到95%,并转化为重要的化学原料,包括苯酚,1,2-二羟基苯和2-苯氧基苯酚。随后,在法拉第效率接近100%的CoP NWs / CC阴极上产生氢。Co的超亲水表面的协同作用3 O 4 NWs / CC阳极和CoP NWs / CC阴极以及阴极的超疏水性确保了电解质溶液和活性材料的充分接触,并确保了H 2气泡的高效生成。
更新日期:2017-12-11
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