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Recent developments in the metallo-supramolecular chemistry of oligo-β-diketonato ligands
Coordination Chemistry Reviews ( IF 20.6 ) Pub Date : 2017-12-11 , DOI: 10.1016/j.ccr.2017.11.007
Aidan J. Brock , Jack K. Clegg , Feng Li , Leonard F. Lindoy

Classical β-diketone ligands have been well demonstrated to exhibit a rich metal coordination chemistry yielding metal complexes displaying a variety of properties. The investigation of polydentate ligand derivatives containing more than one β-diketone domain, and in many instances also incorporating additional donor sites, have been demonstrated to react with a range of metal ion types to yield a wide range of metallo-supramolecular topologies. These include metallocyclic platforms, triangles, squares, cubes, helicates, tetrahedrons as well as other intricate structures that include a universal 3-ravel. In this report we cover the published literature in the area from 2008 with emphasis on the synthetic strategies employed as well as on the diverse structures of the metallo-supramolecular products obtained.



中文翻译:

β-二酮低聚配体的金属-超分子化学的最新进展

经典的β-二酮配体已被很好地证明具有丰富的金属配位化学作用,可产生具有多种特性的金属络合物。含一个以上β的多齿配体衍生物的研究-二酮结构域,并且在许多情况下还结合了其他供体位点,已被证明可与多种金属离子类型反应以产生多种金属-超分子拓扑。这些包括金属环平台,三角形,正方形,立方体,螺旋形,四面体以及其他复杂的结构,其中包括通用的3阶。在本报告中,我们涵盖了2008年以来该地区的已发表文献,重点介绍了所采用的合成策略以及所获得的金属超分子产物的不同结构。

更新日期:2018-06-03
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