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Ni-Catalyzed Formal Carbonyl-Ene Reaction of Terminal Alkenes via Carbon Dioxide Insertion
Synlett ( IF 2 ) Pub Date : 2017-12-08 , DOI: 10.1055/s-0036-1591845
Masanari Kimura 1 , Yasuyuki Mori 2 , Chieko Shigeno 1 , Ying Luo 1 , Bun Chan 1 , Gen Onodera 1
Affiliation  

Nickel catalyzes the multicomponent coupling reaction of terminal alkenes, carbon dioxide, and organoaluminum reagents, leading to the synthesis of homoallylic alcohols in moderate-to-good yields with excellent regio- and stereoselectivities.

中文翻译:

通过二氧化碳插入的镍催化末端烯烃的甲醛羰基-烯反应

镍催化末端烯烃、二氧化碳和有机铝试剂的多组分偶联反应,从而以中等至良好的收率合成均烯丙醇,并具有出色的区域和立体选择性。
更新日期:2017-12-08
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