Ligand dependent assembly of trinuclear titanium-oxo units into coordination tetrahedra and capsules†,Dalton Transactions

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Ligand dependent assembly of trinuclear titanium-oxo units into coordination tetrahedra and capsules†
Dalton Transactions ( IF 4 ) Pub Date : 2017-12-05 00:00:00 , DOI: 10.1039/c7dt04204c
Xi Fan _{1,

2,

3,

4,

5} , Nagaraju Narayanam _{1,

2,

3,

4,

5} , Meiyan Gao _{1,

2,

3,

4,

5} , Lei Zhang _{1,

2,

3,

4,

5} , Jian Zhang _{1,

2,

3,

4,

5}

Affiliation

In the presence of phosphorous acid and by selecting different bridging ligands, trinuclear Ti₃(μ₃-O) units have been assembled into coordination cages with topologies such as {Ti₆} clusters, {Ti₉Cu} tetrahedrons and {Ti₁₈} capsules.

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