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Eu-doped ZnO nanoparticles: Sonochemical synthesis, characterization, and sonocatalytic application.
Ultrasonics Sonochemistry ( IF 8.4 ) Pub Date : 2015-03-30 , DOI: 10.1016/j.ultsonch.2015.03.016
Alireza Khataee 1 , Atefeh Karimi 1 , Mahmoud Zarei 2 , Sang Woo Joo 3
Affiliation  

Undoped and europium (III)-doped ZnO nanoparticles were prepared by a sonochemical method. The prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) analysis. The crystalline sizes of undoped and 3% Eu-doped ZnO were found to be 16.04 and 8.22 nm, respectively. The particle size of Eu-doped ZnO nanoparticles was much smaller than that of pure ZnO. The synthesized nanocatalysts were used for the sonocatalytic degradation of Acid Red 17. Among the Eu-doped ZnO catalysts, 3% Eu-doped ZnO nanoparticles showed the highest sonocatalytic activity. The effects of various parameters such as catalyst loading, initial dye concentration, pH, ultrasonic power, the effect of oxidizing agents, and the presence of anions were investigated. The produced intermediates of the sonocatalytic process were monitored by GC–Mass (GC–MS) spectrometry.



中文翻译:

-掺杂的ZnO纳米粒子:声化学合成,表征和声催化应用。

通过声化学方法制备了未掺杂和and(III)掺杂的ZnO纳米颗粒。通过X射线衍射(XRD),扫描电子显微镜(SEM)和X射线光电子能谱(XPS)分析对制备的样品进行表征。发现未掺杂和3%Eu掺杂的ZnO的晶体尺寸分别为16.04nm和8.22nm。Eu掺杂的ZnO纳米粒子的粒径比纯ZnO的粒径小得多。合成的纳米催化剂用于酸性红17的声催化降解。在Eu掺杂的ZnO催化剂中,3%Eu掺杂的ZnO纳米颗粒具有最高的声催化活性。研究了催化剂负载,初始染料浓度,pH,超声功率,氧化剂的影响以及阴离子的存在等各种参数的影响。

更新日期:2015-03-30
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