For the first time, the RAFT polymerization of a monomeric ionic liquid under hard confinement was successfully carried out. Consequently, macromolecules with well-defined chemical structures and narrow molecular weight distributions were obtained. Additionally, we reported the unique possibility of triggering RAFT polymerization at 30 °C. This novel strategy open alternative routes to the easy and simple manufacturing of polymers with defined geometries and highly specific properties according to our desired purpose, i.e., in industrial application as biosensors and electronic and electrical nanodevices.

中文翻译：

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硬约束对单体离子液体RAFT聚合作用的研究。在30°C时意外触发RAFT聚合

首次成功地在硬约束下成功进行了单体离子液体的RAFT聚合。因此，获得具有明确的化学结构和窄的分子量分布的大分子。此外，我们报道了在30°C引发RAFT聚合的独特可能性。根据我们期望的目的，即在工业应用中作为生物传感器以及电子和电子纳米器件，这种新颖的策略为具有定义的几何形状和高度特定的特性的聚合物的简便制造提供了替代途径。