In this review article, we highlight over 25 years of fullerene research in charge transfer chemistry. The major thrust of this work is to illustrate interfacial interactions between fullerenes and porphyrins in electron donor–acceptor conjugates as well as self-assembled associates and co-crystallites all the way to organic photovoltaics. Hereby, the analysis of the fundamental proceses, namely, energy transfer, charge shift, charge separation as well as charge recombination stand at the forefront. Our examples, illustrate on how fine-tuning the structure leads to substantial alteration of interfacial interactions.

中文翻译：

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富勒烯– 25年的电荷转移化学如何塑造了我们对（界面）相互作用的理解

在这篇评论文章中，我们重点介绍了富勒烯在电荷转移化学领域超过25年的研究。这项工作的主要目的是说明富勒烯与卟啉之间在电子给体-受体共轭物以及自组装的缔合体和共晶体直至有机光伏中的界面相互作用。因此，对基本过程的分析，即能量转移，电荷转移，电荷分离以及电荷复合，始终处于最前沿。我们的示例说明了如何微调结构导致界面相互作用的实质性改变。