The cleavage of both sp² C−H and C−N bonds by a nickel‐catalyzed reaction of aromatic amides containing an 8‐aminoquinoline moiety with benzyl ammonium salts is reported. A wide variety of functional groups are tolerated in the reaction. Preliminary mechanistic investigations indicate that the reaction probably proceeds through a Ni^I/Ni^III catalytic pathway. This Ni‐catalyzed procedure provides an alternative approach to construct diarylmethane derivatives.

中文翻译：

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通过C-H / C-N裂解的镍催化芳族酰胺中邻位C-H键的直接苯甲酰化

据报道，通过镍催化的含8-氨基喹啉部分的芳香酰胺与苄基铵盐的反应，sp ^2的C H和C N键均被裂解。在反应中可以容忍各种各样的官能团。初步的机理研究表明，该反应可能通过Ni ^I / Ni ^III催化途径进行。这种镍催化的方法为构建二芳基甲烷衍生物提供了另一种方法。