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Radical halogenation-mediated latent–active glycosylations of allyl glycosides
Chemical Communications ( IF 4.9 ) Pub Date : 2017-11-27 00:00:00 , DOI: 10.1039/c7cc07332a
Rita Pal 1, 2, 3, 4 , Anupama Das 1, 2, 3, 4 , Narayanaswamy Jayaraman 1, 2, 3, 4
Affiliation  

Radical halogenation-mediated glycosylation using allyl glycosides as donors and as acceptors emerges to be an efficient and hither-to unknown glycosylation method, adhering to the concept of the latent–active methodology. Several di- and trisaccharides that possess the allyl moiety at their reducing end are prepared through this new glycosylation methodology.

中文翻译:

自由基卤代介导的烯丙基糖苷的潜伏活性糖基化

使用烯丙基糖苷作为供体和受体的自由基卤代介导的糖基化方法是一种有效且迄今未知的糖基化方法,它秉承了潜伏性-活性方法学的概念。通过这种新的糖基化方法制备了几种在其还原端具有烯丙基部分的二糖和三糖。
更新日期:2018-01-16
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