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An easier and quicker access to (benzenesulfonyl)difluoromethanesulfenamide reagent
Journal of Fluorine Chemistry ( IF 1.9 ) Pub Date : 2017-07-05 , DOI: 10.1016/j.jfluchem.2017.07.001
Ermal Ismalaj , Thierry Billard

(Benzenesulfonyl)difluoromethanesulfenamide (PhSO2-BB12H) is an interesting reagent to lead to various fluoroalkylselenotated molecules. This compound is obtained from [(benzenesulfonyl)difluoromethyl]trimethylsilane. Herein, a new process in two steps, without intermediate purifications, is described to easily synthesize this product. With this new method, preparation of PhSO2-BB12H reagent has been carried out in only 3 steps, with only one final purification and with a good overall yield.



中文翻译:

更容易,更快捷地使用(苯磺酰基)二氟甲烷亚磺酰胺试剂

(苯磺酰基)二氟甲亚磺酰胺PhSO2-BB12H)是引起各种氟代烷基代化分子的有趣试剂。该化合物由[(苯磺酰基)二氟甲基]三甲基硅烷获得。在此,描述了不经中间纯化就分两步进行的新方法,以容易地合成该产物。使用这种新方法,仅需3个步骤即可完成PhSO2-BB12H试剂的制备,仅需进行一次纯化即可,并且具有良好的总收率。

更新日期:2017-07-05
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