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Ammonium Tungstate as an Effective Catalyst for Selective Oxidation of Alcohols to Aldehydes or Ketones with Hydrogen Peroxide under Water – A Synergy of Graphene Oxide
Synlett ( IF 2 ) Pub Date : 2017-11-17 , DOI: 10.1055/s-0036-1590949 Xinhua Peng , Huihui Fu , Chuanfeng Hu , Zhida Huang , Jianhao Zhou
Synlett ( IF 2 ) Pub Date : 2017-11-17 , DOI: 10.1055/s-0036-1590949 Xinhua Peng , Huihui Fu , Chuanfeng Hu , Zhida Huang , Jianhao Zhou
Ammonium tungstate was found to be a facile and efficient catalyst for selective oxidation of alcohols to the corresponding carbonyl compounds with hydrogen peroxide as oxidant. Heterogeneous graphene oxide as acid effectively intensified the transformations and resulted in excellent yields. The use of water as solvent rendered the reactions promising both economically and environmentally.
中文翻译:
钨酸铵作为一种有效的催化剂,用于在水下用过氧化氢将醇选择性氧化成醛或酮——氧化石墨烯的协同作用
发现钨酸铵是一种简便而有效的催化剂,用于将醇选择性氧化为相应的羰基化合物,过氧化氢作为氧化剂。作为酸的多相氧化石墨烯有效地加强了转化并产生了优异的产率。使用水作为溶剂使得反应在经济和环境上都有前景。
更新日期:2017-11-17
中文翻译:
钨酸铵作为一种有效的催化剂,用于在水下用过氧化氢将醇选择性氧化成醛或酮——氧化石墨烯的协同作用
发现钨酸铵是一种简便而有效的催化剂,用于将醇选择性氧化为相应的羰基化合物,过氧化氢作为氧化剂。作为酸的多相氧化石墨烯有效地加强了转化并产生了优异的产率。使用水作为溶剂使得反应在经济和环境上都有前景。