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Mobilities of Li+-attached butanol isomers in helium gas at 85.5 K
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2017-11-21 , DOI: 10.1016/j.cplett.2017.11.036
K. Takahashi , K.M. Moriya , S. Matoba , T. Koizumi , H. Tanuma

Mobilities of Li+-attached butanol isomers, (n-BuOH)Li+, (s-BuOH)Li+, (i-BuOH)Li+, and (t-BuOH)Li+, in helium gas cooled by liquid nitrogen were measured in reduced electric fields E/N=E/N= 8-65 Td. Together with previous measurements at room temperature, the results cover a range of collision energies (ε=ε= 10-130 meV). Differences in the mobilities of the isomers became pronounced at low collision energies; for example, (n-BuOH)Li+ showed a mobility about 5 % greater than (t-BuOH)Li+ at 10 meV.



中文翻译:

85.5 K下氦气中与Li +相连的丁醇异构体的迁移率

在液态氮冷却的氦气中,与Li +相连的丁醇异构体(n -BuOH)Li +,(s- BuOH)Li +,(i- BuOH)Li +和(t- BuOH)Li +的迁移率分别为在减小的电场中测得E / N =E/ñ=8-65吨 加上先前在室温下的测量结果,结果涵盖了一定范围的碰撞能量(ε=ε=10-130 meV)。在低碰撞能量下,异构体的迁移率差异变得明显。例如,在10 meV下,(n -BuOH)Li +的迁移率比(t -BuOH)Li +大约5%。

更新日期:2017-11-21
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