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Efficient light hydrocarbon separation and CO2 capture and conversion in a stable MOF with oxalamide-decorated polar tubes
Chemical Communications ( IF 4.9 ) Pub Date : 2017-11-21 00:00:00 , DOI: 10.1039/c7cc08298c
Xiu-Yuan Li 1, 2, 3, 4, 5 , Yong-Zhi Li 1, 2, 3, 4, 5 , Yun Yang 1, 2, 3, 4, 5 , Lei Hou 1, 2, 3, 4, 5 , Yao-Yu Wang 1, 2, 3, 4, 5 , Zhonghua Zhu 6, 7, 8, 9
Affiliation  

The first strontium-based MOF possessing polar tubular channels embedded with a high density of open Lewis acidic metal sites and basic oxalamide groups was constructed, which shows not only a high CO2 and C2H6 adsorption capability and significant selectivity for CO2 over both CH4 and CO, and for C2H6 over CH4, but also size-selective chemical conversion of CO2 with epoxides producing cyclic carbonates under ambient conditions.

中文翻译:

用草酰胺修饰的极性管在稳定的MOF中有效地进行轻烃分离以及CO 2的捕集和转化

第一锶-基于MOF具有嵌入开放路易斯酸性的金属位点和碱性草酰胺基团的高密度极性管状通道构造,其示出了不仅具有高CO 2和C 2 H ^ 6吸附能力和显著选择性CO 2过CH 4和CO,以及C 2 H 6超过CH 4的情况,还包括在环境条件下用环氧化物进行的CO 2的尺寸选择化学转化,生成环状碳酸酯。
更新日期:2017-12-01
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