Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs,Chemical Communications

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Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
Chemical Communications ( IF 4.9 ) Pub Date : 2017-11-06 00:00:00 , DOI: 10.1039/c7cc06022j
Luke C. Delmas _{1,

2,

3,

4,

5} , Peter N. Horton _{1,

6,

7,

8,

9} , Andrew J. P. White _{1,

2,

3,

4,

5} , Simon J. Coles _{1,

6,

7,

8,

9} , Paul D. Lickiss _{1,

2,

3,

4,

5} , Robert P. Davies _{1,

2,

3,

4,

5}

Affiliation

A siloxane-based hexacarboxylic acid (L1-H₆) has been prepared and applied in MOF construction. L1-H₆ itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H₆ with Zn(II) gave IMP-18 – a 3D MOF incorporating Si–O–Si functionality. Cleavage of L1-H₆ gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(II).

中文翻译：

氢键组装和多孔3D MOF的构建中基于硅氧烷的接头

已经制备了基于硅氧烷的六羧酸（L1- H ₆）并将其应用于MOF构造中。L1- H ₆本身结晶为不寻常的互穿3D氢键骨架。L1- H ₆与Zn（II）的反应产生了IMP-18 –一种结合了Si–O–Si功能的3D MOF。L1- H _6的裂解得到基于硅烷醇的三酸，其显示出与锌（II）的配位聚合物（IMP-19）。

更新日期：2017-11-21

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