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Structural reconstruction: a milestone in the hydrothermal synthesis of highly active Sn-Beta zeolites
Chemical Communications ( IF 4.9 ) Pub Date : 2017-10-31 00:00:00 , DOI: 10.1039/c7cc06778j Zhiguo Zhu 1, 2, 3, 4 , Hao Xu 1, 2, 3, 4 , Jingang Jiang 1, 2, 3, 4 , Haihong Wu 1, 2, 3, 4 , Peng Wu 1, 2, 3, 4
Chemical Communications ( IF 4.9 ) Pub Date : 2017-10-31 00:00:00 , DOI: 10.1039/c7cc06778j Zhiguo Zhu 1, 2, 3, 4 , Hao Xu 1, 2, 3, 4 , Jingang Jiang 1, 2, 3, 4 , Haihong Wu 1, 2, 3, 4 , Peng Wu 1, 2, 3, 4
Affiliation
A novel structural reconstruction strategy is proposed to prepare an active Sn-Beta catalyst with high Sn contents and a hydrophobic nature. Compared with post-synthesized Sn-Beta and state-of-the-art classic fluoride-mediated Sn-Beta-F, this Sn-Beta zeolite exhibits unparalleled active site-based turnover frequency for desirable products and in particular catalyst weight-based space-time-yields in various redox reactions of ketones.
中文翻译:
结构重建:水热合成高活性Sn-Beta沸石的里程碑
提出了一种新颖的结构重构策略,以制备具有高锡含量和疏水性的活性锡-β-催化剂。与后合成的Sn-Beta和最先进的经典氟化物介导的Sn-Beta-F相比,这种Sn-Beta沸石表现出无与伦比的活性位点转换频率,可满足所需产品的需求,尤其是基于催化剂重量的空间酮的各种氧化还原反应中的高时产率。
更新日期:2017-11-21
中文翻译:
结构重建:水热合成高活性Sn-Beta沸石的里程碑
提出了一种新颖的结构重构策略,以制备具有高锡含量和疏水性的活性锡-β-催化剂。与后合成的Sn-Beta和最先进的经典氟化物介导的Sn-Beta-F相比,这种Sn-Beta沸石表现出无与伦比的活性位点转换频率,可满足所需产品的需求,尤其是基于催化剂重量的空间酮的各种氧化还原反应中的高时产率。