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A surprising substituent effect in corroles on the electrochemical activation of oxygen reduction
Chemical Communications ( IF 4.9 ) Pub Date : 2017-11-10 00:00:00 , DOI: 10.1039/c7cc06920k
Naomi Levy 1, 2, 3, 4 , Jennifer S. Shpilman 1, 2, 3, 4 , Hilah C. Honig 1, 2, 3, 4 , Dan T. Major 1, 2, 3, 4 , Lior Elbaz 1, 2, 3, 4
Affiliation  

Four β-pyrrole-substituted cobalt(III) corroles were studied as electrocatalysts for the oxygen reduction reaction. The results disclose high dependence of the corrole's performance on its substituents, but once adsorbed on a high surface area carbon, this effect vanishes, resulting in a better catalytic performance than most well-defined molecular electrocatalysts for this reaction.

中文翻译:

腐蚀中令人惊讶的取代基对氧还原的电化学活化的作用

研究了四种β-吡咯取代的钴(III)烷氧基作为氧还原反应的电催化剂。结果表明,该甲氧基的性能高度依赖于其取代基,但是一旦吸附在高表面积的碳上,该作用就消失了,与该反应的大多数明确定义的分子电催化剂相比,其催化性能更好。
更新日期:2017-11-20
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