Gold-Catalyzed Asymmetric Intramolecular Cyclization of N-Allenamides for the Synthesis of Chiral Tetrahydrocarbolines,Angewandte Chemie International Edition

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Gold-Catalyzed Asymmetric Intramolecular Cyclization of N-Allenamides for the Synthesis of Chiral Tetrahydrocarbolines
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-11-20 05:41:31 , DOI: 10.1002/anie.201709595
Yidong Wang ₁ , Peichao Zhang ₁ , Xiaoyu Di ₁ , Qiang Dai ₁ , Zhan-Ming Zhang ₁ , Junliang Zhang _{1,

2}

Affiliation

Ringing the changes: The first example of highly enantioselective gold-catalyzed intramolecular cyclization of N-allenamides was implemented by utilizing PC-Phos ligands. The utility of this reaction was validated by the total synthesis of (R)-desbromoarborescidine A.

中文翻译：