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Efficient Water Reduction with sp3-sp3 Diboron(4) Compounds: Application to Hydrogenations, H–D Exchange Reactions, and Carbonyl Reductions
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-11-17 05:21:17 , DOI: 10.1002/anie.201709685
Mathias Flinker 1 , Hongfei Yin 1 , René W. Juhl 1 , Espen Z. Eikeland 1 , Jacob Overgaard 1 , Dennis U. Nielsen 1 , Troels Skrydstrup 1
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(B)reaking (B)ad: The reported sp3-sp3 diboron(4) compounds are capable of reducing water to dihydrogen. The produced gas has been utilized in a variety of reductive transformations. Furthermore, a selection of aldehydes and ketones can be reduced in the presence of such diboron compounds in water by the presence of an intermediary borohydride species.

中文翻译:

sp3-sp3 Diboron(4)化合物的高效减水作用:在加氢,H–D交换反应和羰基还原反应中的应用

(B)ad(B)ad:报道的sp 3 -sp 3 diboron(4)化合物能够将水还原为二氢。产生的气体已用于多种还原转化中。此外,在水中存在这样的二硼化合物时,可以通过存在中间的硼氢化物来减少对醛和酮的选择。
更新日期:2017-11-17
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