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Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2017-11-14 00:00:00 , DOI: 10.1021/acs.joc.7b02221
Shiping Yang 1 , Boya Feng 1 , Yudong Yang 1
Affiliation  

A highly efficient Rh(III)-catalyzed direct C–H chalcogenation of phenols and anilines has been achieved with the assistance of the 2-pyridyl group. The reaction features a broad substrate scope, good functional group tolerance, complete monothiolation selectivity, and easily removable directing group.

中文翻译:

Rh(III)催化的苯酚和苯胺直接邻位硫醇化

在2-吡啶基的帮助下,高效的Rh(III)催化的苯酚和苯胺的C–H直接硫族元素化。该反应具有广泛的底物范围,良好的官能团耐受性,完全的单硫醇选择性和易于除去的导向基团。
更新日期:2017-11-16
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