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Experimental Studies on the Effect of Tertiary Amine Promoters in Aqueous Monoethanolamine (MEA) Solutions on the Absorption/Stripping Performances in Post-combustion CO2 Capture
Energy & Fuels ( IF 5.3 ) Pub Date : 2017-11-29 00:00:00 , DOI: 10.1021/acs.energyfuels.7b02390
Hongxia Gao 1 , Zeyang Wu 1 , Helei Liu 1 , Xiao Luo 1 , Zhiwu Liang 1
Affiliation  

The absorption/desorption performance of carbon dioxide (CO2) in aqueous 5 M monoethanolamine (MEA) solutions in the presence of various solution regeneration promoters was comprehensively investigated using a multiple rapid screening method. The promoters considered were N-methyldiethanolamine (MDEA), N,N-dimethylethanolamine (DMEA), N,N-diethylethanolamine (DEEA), 1-dimethylamino-2-propanol (1DMA2P), 1-diethylamino-2-propanol (1DEA2P), 3-dimethylamino-1-propanol (3DMA1P), 2-(dimethylamino)-2-methyl-1-propanol (2DMA2M1P), triethanolamine (TEA), 3-(dimethylamino)-1,2-propanediol (3DMA-1,2-PD), and 3-(diethylamino)-1,2-propanediol (3DEA-1,2-PD). The molar concentration of these promoters added into 5 M MEA was set to 1 mol/L. At the atmospheric pressure, the absorption and stripping experiments were carried out at 313.15 and 353.15 K, respectively. Especially, the CO2 partial pressure was controlled at constant 15 kPa for absorption experiments. In addition, the equilibrium solubility of CO2 was also determined in order to evaluate the driving force of each amine system. The results showed that the highest CO2 equilibrium solubility of 0.5548 mol CO2/mol amine was obtained by MEA/1DEA2P, whereas both the fastest absorption and regeneration rates were achieved for aqueous blended MEA/1DMA2P solution which made MEA/1DMA2P to exhibit the highest CO2 cyclic capacity of 1.6710 mol CO2/L.

中文翻译:

单乙醇胺水溶液中叔胺促进剂对燃烧后CO 2捕集吸收/剥离性能影响的实验研究

使用多种快速筛选方法全面研究了5 M单乙醇胺(MEA)水溶液中在各种溶液再生促进剂存在下二氧化碳(CO 2)的吸收/解吸性能。考虑的启动子是N-甲基二乙醇胺(MDEA),NN-二甲基乙醇胺(DMEA),NN-二乙基乙醇胺(DEEA),1-二甲基氨基-2-丙醇(1DMA2P),1-二乙基氨基-2-丙醇(1DEA2P),3-二甲基氨基-1-丙醇(3DMA1P),2-(二甲基氨基)-2-甲基-1 -丙醇(2DMA2M1P),三乙醇胺(TEA),3-(二甲氨基)-1,2-丙二醇(3DMA-1,2-PD)和3-(二乙氨基)-1,2-丙二醇(3DEA-1,2 -PD)。将这些促进剂添加到5 M MEA中的摩尔浓度设为1 mol / L。在大气压下,吸收和汽提实验分别在313.15和353.15 K下进行。特别地,为了吸收实验,将CO 2分压控制在恒定的15kPa。此外,还确定了CO 2的平衡溶解度,以便评估每种胺系统的驱动力。结果表明,最高的COMEA / 1DEA2P的2平衡溶解度为0.5548 mol CO 2 / mol胺,而MEA / 1DMA2P水性共混溶液的吸收和再生速率均达到最快,这使得MEA / 1DMA2P表现出最高的CO 2循环容量1.6710摩尔CO 2 / L。
更新日期:2017-11-29
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