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A Molecular Level Understanding of Template Effects in Ionic Liquids
Accounts of Chemical Research ( IF 18.3 ) Pub Date : 2017-11-13 00:00:00 , DOI: 10.1021/acs.accounts.7b00436
Roman Elfgen 1, 2 , Oldamur Hollóczki 1 , Barbara Kirchner 1
Affiliation  

The structure-directing or template effect has been invoked several times for ionic liquids to explain the different outcome in material synthesis, namely, different scaffolds or geometrical arrangements with varying ionic liquids. It is obvious to assume that such an effect can originate from the most likely complex microstructure, being present within the ionic liquid itself. In that regard, ionic liquids have already been shown to undergo a nanosegregation into polar and nonpolar phases, which is commonly known and denoted as microheterogeneity.

中文翻译:

分子水平对离子液体中模板作用的理解

对于离子液体,已经多次调用了结构导向或模板效应,以解释材料合成中的不同结果,即具有不同离子液体的不同支架或几何排列。显然,可以假定这种效应可能是由于离子液体本身中存在的最可能的复杂微观结构引起的。在这方面,已经证明离子液体经历纳米分离成极性和非极性相,这是众所周知的,并表示为微异质性。
更新日期:2017-11-13
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