Abstract

Carbon dioxide is not only an essential component of ‘greenhouse gases’, but also an abundant, renewable C1 feedstock in organic synthesis. The catalytic incorporation of carbon dioxide into value-added chemicals to produce carboxylic acids has received enormous attention. This review summarizes recent developments in the transition-metal-catalyzed carboxylation of organic halides and their surrogates, such as aryl, vinyl, and alkyl halides and pseudohalides.

1 Introduction

2 Carboxylation of Aryl Halides and Pseudohalides

3 Carboxylation of Vinyl Halides and Pseudohalides

4 Carboxylation of Benzyl Halides and Pseudohalides

5 Carboxylation of Allyl Halides and Pseudohalides

6 Carboxylation of Propargyl Halides and Pseudohalides

7 Carboxylation of Alkyl Halides and Pseudohalides

8 Direct Carboxylation of C–H Bonds

9 Conclusions and Perspectives

Carbon dioxide is not only an essential component of ‘greenhouse gases’, but also an abundant, renewable C1 feedstock in organic synthesis. The catalytic incorporation of carbon dioxide into value-added chemicals to produce carboxylic acids has received enormous attention. This review summarizes recent developments in the transition-metal-catalyzed carboxylation of organic halides and their surrogates, such as aryl, vinyl, and alkyl halides and pseudohalides.

1 Introduction

2 Carboxylation of Aryl Halides and Pseudohalides

3 Carboxylation of Vinyl Halides and Pseudohalides

4 Carboxylation of Benzyl Halides and Pseudohalides

5 Carboxylation of Allyl Halides and Pseudohalides

6 Carboxylation of Propargyl Halides and Pseudohalides

7 Carboxylation of Alkyl Halides and Pseudohalides

8 Direct Carboxylation of C–H Bonds

9 Conclusions and Perspectives

中文翻译：

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过渡金属催化的有机卤化物及其代用品与二氧化碳的羧化反应

摘要

二氧化碳不仅是“温室气体”的重要组成部分，而且还是有机合成中大量可再生的C1原料。将二氧化碳催化并入增值化学品中以生产羧酸受到了极大的关注。这篇综述总结了过渡金属催化的有机卤化物及其替代物（例如芳基，乙烯基和烷基卤化物和假卤化物）羧化的最新进展。

1引言

2芳基卤化物和假卤化物的羧化

3乙烯基卤化物和伪卤化物的羧化

4卤化苄和伪卤的羧化

5烯丙基卤化物和伪卤化物的羧化

6炔丙基卤化物和拟卤化物的羧基化

7烷基卤化物和假卤化物的羧化

8 C–H键的直接羧基化

9结论与观点

二氧化碳不仅是“温室气体”的重要组成部分，而且还是有机合成中大量可再生的C1原料。将二氧化碳催化并入增值化学品中以生产羧酸受到了极大的关注。这篇综述总结了过渡金属催化的有机卤化物及其替代物（例如芳基，乙烯基和烷基卤化物和假卤化物）羧化的最新进展。

1引言

2芳基卤化物和假卤化物的羧化

3乙烯基卤化物和伪卤化物的羧化

4卤化苄和伪卤的羧化

5烯丙基卤化物和伪卤化物的羧化

6炔丙基卤化物和拟卤化物的羧基化

7烷基卤化物和假卤化物的羧化

8 C–H键的直接羧基化

9结论与观点