A series of molybdenum oxide supported on ordered mesoporous zirconium oxophosphate (MoO₃/M-ZrPO) materials with different MoO₃ loadings (0–20 wt%) and calcination temperatures (500–900 °C) have been designed, synthesized and employed as solid acid catalysts in alkylation and esterification. The XRD, TG-DSC, H₂-TPR, N₂-physisorption and TEM characterizations were taken to investigate the structural properties and states of introduced MoO₃ species. The influence of MoO₃ loadings and calcination temperatures in catalytic performance was detailedly investigated and optimal catalytic activity was reached at 10 wt% MoO₃ loadings and treated at 700 °C. Moreover, MoO₃/M-ZrPO catalysts exhibited outstanding catalytic performance in Friedel-Crafts alkylation of different aromatic compounds and esterification of levulinic acid with 1-butanol. Furthermore, it was noteworthy that the catalyst had superior reusability and no noticeable declines were observed in catalytic performance even after seven runs.

设计，合成和使用了一系列负载在有序中孔含氧磷酸锆（MoO ₃ / M-ZrPO）材料上的氧化钼，这些材料具有不同的MoO ₃负载量（0–20 wt％）和煅烧温度（500–900°C）。固体酸催化剂的烷基化和酯化反应。通过XRD，TG-DSC，H ₂ -TPR ，N _2-物理吸附和TEM表征研究了引入的MoO ₃的结构性质和状态。详细研究了MoO _3的负载量和煅烧温度对催化性能的影响，并在10 wt％MoO _3的条件下达到了最佳的催化活性。负载并在700°C下处理。此外，MoO ₃ / M-ZrPO催化剂在不同芳族化合物的Friedel-Crafts烷基化反应和乙酰丁酸与1-丁醇的酯化反应中表现出出色的催化性能。此外，值得注意的是，该催化剂具有优异的可重复使用性，即使经过七次运行也未观察到催化性能的明显下降。