Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2017-11-07 , DOI: 10.1016/j.jeurceramsoc.2017.10.037 Hongbin Su , Yu Nie , Hsiwen Yang , Dian Tang , Kongfa Chen , Teng Zhang
In this work, a phosphor for white light-emitting diode (LED) application, Ce3+-doped yttrium aluminum garnet (YAG:Ce3+), was successfully packaged using a P2O5-ZnO-Na2O-Al2O3 glass-ceramic system, through a vertical deposition method. Here, we found that white light can be achieved by combining the packaged phosphor with a blue chip (e.g. InGaN). The specimen doped with 4 mol% Al2O3 showed a luminous efficacy (LE) of 125.8 lm W−1, at a correlated color temperature (CCT) of 5769 K, with a color rendering index (CRI) of 68. In addition, the LE loss of the specimen doped with 4 mol% Al2O3 was only 3.6% after heat treatment at 150 °C for 1200 h, which is significantly lower than that of traditional resin (19.3%). Moreover, a possible mechanism for reducing the LE loss using glass-ceramics was proposed.
中文翻译:
玻璃陶瓷改善白色发光二极管(LED)中磷光体的热稳定性:Al 2 O 3掺杂剂的作用
在这项工作中,成功地使用P 2 O 5 -ZnO-Na 2 O-Al包装了用于白色发光二极管(LED)的荧光粉,掺杂Ce 3+的钇铝石榴石(YAG:Ce 3+)。2 O 3玻璃陶瓷系统,通过垂直沉积方法。在这里,我们发现可以通过将封装的荧光粉与蓝色芯片(例如InGaN)结合使用来获得白光。掺有4 mol%Al 2 O 3的样品的发光效率(LE)为125.8 lm W -1,在相关色温(CCT)为5769 K时,显色指数(CRI)为68。此外,掺有4 mol%Al 2 O 3的样品在150°C热处理后的LE损耗仅为3.6%。 150°C持续1200 h,大大低于传统树脂的温度(19.3%)。此外,提出了一种使用玻璃陶瓷减少LE损耗的可能机制。