Purinyl-cobamide is a native prosthetic group of reductive dehalogenases,Nature Chemical Biology

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Purinyl-cobamide is a native prosthetic group of reductive dehalogenases
Nature Chemical Biology ( IF 14.8 ) Pub Date : 2017-11-06 , DOI: 10.1038/nchembio.2512
Jun Yan , Meng Bi , Allen K Bourdon , Abigail T Farmer , Po-Hsiang Wang , Olivia Molenda , Andrew T Quaile , Nannan Jiang , Yi Yang , Yongchao Yin , Burcu Şimşir , Shawn R Campagna , Elizabeth A Edwards , Frank E Löffler

Purinyl-cobamide is a native prosthetic group of reductive dehalogenases

Purinyl-cobamide is a native prosthetic group of reductive dehalogenases, Published online: 06 November 2017; doi:10.1038/nchembio.2512

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In organohalide-respiring bacteria, reductive dehalogenases cleave carbon–halogen bonds using cobamide prosthetic groups. Desulfitobacterium hafniense uses an unprecedented cobamide variant, which includes unsubstituted purine, for this function.

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