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Hydrogen Evolution by FeIII Molecular Electrocatalysts Interconverting between Mono and Di-Nuclear Structures in Aqueous Phase
ChemSusChem ( IF 8.4 ) Pub Date : 2017-11-09 12:30:41 , DOI: 10.1002/cssc.201701612
Mirko Tagliapietra 1 , Andrea Squarcina 1 , Neal Hickey 2 , Rita De Zorzi 2 , Silvano Geremia 2 , Andrea Sartorel 1 , Marcella Bonchio 1
Affiliation  

Iron for Hydrogen: Mononuclear/ dinuclear Fe species under pH-triggered equilibrium catalyze electrocatalytic hydrogen evolution in trifluoroacetic acid (TFA)/CH3CN or CH3CN/acetate buffer with icat/ip values in the range 15–28 (icat is the catalytic current, whereas ip is the current of an Fe-based redox event).

中文翻译:

FeIII分子电催化剂在单相和双核结构在水相中互变氢

氢气中的铁:pH触发平衡下的单核/双核铁物种在三氟乙酸(TFA)/ CH 3 CN或CH 3 CN /乙酸盐缓冲液中的i cat / i p值在15-28(i cat是催化电流,而i p是铁基氧化还原事件的电流)。
更新日期:2017-11-09
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