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Enhanced performance of the dye-sensitized solar cells by the introduction of graphene oxide into the TiO2 photoanode
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2017-10-25 00:00:00 , DOI: 10.1039/c7qi00503b
Liguo Wei 1, 2, 3, 4, 5 , Ping Wang 4, 6, 7, 8, 9 , Yulin Yang 4, 6, 7, 8, 9 , Zhaoshun Zhan 1, 2, 3, 4 , Yongli Dong 1, 2, 3, 4 , Weina Song 1, 2, 3, 4 , Ruiqing Fan 4, 6, 7, 8, 9
Affiliation  

In order to enhance the performance of the dye-sensitized solar cells (DSSCs), graphene oxide (GO) was introduced into the TiO2 photoanode to construct a GO-TiO2 composited photoanode. The photoelectric properties of the as-constructed photoanode were studied in comparison with those of the TiO2 photoanode and the effect of GO obtained by different methods on the performance of the GO-TiO2 composited photoanode was also compared. After constructed with GO, the photoanode displayed enhanced light and dye adsorption properties with a higher light harvesting efficiency, lower internal resistances, a faster electron transport, and a lower charge recombination rate, which resulted in a higher current density. At the optimal condition, the DSSCs based on the photoanode modified by GO obtained in our laboratory (GO1) exhibited a Jsc of 18.16 mA cm−2, a Voc of 0.68 V, and a FF of 0.59 with a energy conversion efficiency (η) of 7.30%, indicating an increased performance compared with that of the DSSCs based only on the pure TiO2 photoanode, which had a Jsc of 14.41 mA cm−2, a Voc of 0.66 V, and a FF of 0.60 with a η value of 5.67%. However, when GO that obtained from a production line in a factory (GO2) was used, the performance of the DSSCs was further improved, which showed a Jsc of 19.49 mA cm−2, a Voc of 0.68 V, and an FF of 0.59 with a η value of 7.83%. Different performances between GOs that obtained from the laboratory and the factory were mainly attributed to their distinct production processes, which distinguished their properties from each other. It is a potential method to enhance the performance of the DSSCs by constructing a GO-TiO2 photoanode with a suitable quality GO.

中文翻译:

通过将氧化石墨烯引入TiO 2光阳极来增强染料敏化太阳能电池的性能

为了提高染料敏化太阳能电池(DSSC)的性能,将氧化石墨烯(GO)引入TiO 2光电阳极以构建GO-TiO 2复合光电阳极。与TiO 2光电阳极相比,研究了原态光电阳极的光电性能,以及不同方法获得的GO对GO-TiO 2性能的影响。还比较了复合光阳极。用GO构造后,光电阳极显示出增强的光和染料吸附性能,具有更高的光收集效率,更低的内电阻,更快的电子传输和更低的电荷复合率,从而导致更高的电流密度。在最佳条件下,基于我们实验室(GO1)获得的GO修饰的光阳极的DSSC的J sc为18.16 mA cm -2V oc为0.68 V,FF为0.59,具有能量转换效率(η)的7.30%,表明与仅基于纯的TiO的DSSC中的相比,提高的性能2光电阳极,其中有一个Ĵsc为14.41 mA cm -2 V oc为0.66 V,FF为0.60, η值为5.67%。但是,当使用从工厂的生产线(GO2)获得的GO时,DSSC的性能进一步提高,显示出J sc为19.49 mA cm -2 V oc为0.68 V,FF 0.59, η值为7.83%。从实验室和工厂获得的GO之间的不同性能主要归因于它们不同的生产过程,这使它们的特性彼此不同。通过构建GO-TiO来增强DSSC的性能是一种潜在的方法。2个具有合适质量GO的光电阳极。
更新日期:2017-11-07
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