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Facile synthesis of heterostructured YVO4/g-C3N4/Ag photocatalysts with enhanced visible-light photocatalytic performance
Applied Catalysis B: Environment and Energy ( IF 22.1 ) Pub Date : 2017-11-03 , DOI: 10.1016/j.apcatb.2017.11.003
Yu Gao , Junying Lin , Qingzhe Zhang , He Yu , Fu Ding , Baotong Xu , Yaguang Sun , Zhenhe Xu

A series of YVO4/g-C3N4/Ag composite photocatalysts with various concentrations of YVO4 (YVO4/g-C3N4/Ag) were synthesized for the first time by hydrothermal and the photodeposition method. The photocatalytic activity of the as-prepared YVO4/g-C3N4/Ag composites was evaluated by the degradation of methyl orange (MO) under visible light irradiation. It shows that the photocatalytic activity of g-C3N4 can be largely enhanced by loading Ag nanoparticles (NPs) and YVO4 NPs together. The optimized loading content of YVO4 is 35 wt%, and the highest rate constant shown in 35 wt% YVO4/g-C3N4/Ag is 0.03404 min−1, about 3 times and 2.1 times higher than that in g-C3N4 (0.01131 min−1) and g-C3N4/Ag (0.01613 min−1), respectively. The surface plasmon resonance (SPR) of Ag NPs and efficiently suppressed recombination of charge carriers due to the introduction of YVO4 NPs make the YVO4/g-C3N4/Ag nanocomposite photocatalysts exhibit excellent visible photocatalytic performance and excellent photocatalytic stability. In addition, the trapping experiments using different scavengers showed that the reactive O2 and OH play the major role in the photodegradation of MO.



中文翻译:

简便地合成具有增强的可见光光催化性能的YVO 4 / gC 3 N 4 / Ag异质结构光催化剂

通过水热法和光沉积法首次合成了一系列不同浓度的YVO 4的YVO 4 / gC 3 N 4 / Ag复合光催化剂(YVO 4 / gC 3 N 4 / Ag)。制备的YVO 4 / gC 3 N 4 / Ag复合材料的光催化活性通过在可见光照射下甲基橙(MO)的降解来评估。结果表明,负载Ag纳米颗粒(NPs)和YVO 4可以大大提高gC 3 N 4的光催化活性。NP在一起。YVO 4的最佳负载量为35 wt%,以35 wt%YVO 4 / gC 3 N 4 / Ag显示的最高速率常数 为0.03404 min -1,比gC 3 N高约3倍和2.1倍4(0.01131 min -1)和gC 3 N 4 / Ag(0.01613 min -1)。由于引入了YVO 4 NPs ,Ag NPs的表面等离振子共振(SPR)和有效抑制载流子的重组使YVO 4 / gC 3 N 4成为可能。/ Ag纳米复合光催化剂表现出优异的可见光催化性能和优异的光催化稳定性。此外,使用不同清除剂进行的捕集实验表明,反应性O 2OH在MO的光降解中起主要作用。

更新日期:2017-11-03
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