Catalysis Today ( IF 5.3 ) Pub Date : 2017-10-31 , DOI: 10.1016/j.cattod.2017.10.044 Bo Peng , Chao Feng , Shanshan Liu , Runduo Zhang
CuO catalyst was prepared from HKUST-1 temple through a pyrolysis process, noted as CuO-p. Its morphology with octahedral shape was verified to be inherited from the HKUST-1 and however essentially difference with CuO-c prepared by coprecipitation method. Moreover, CuO-p (15.4 m2/g) obtained by HKUST-1 pyrolysis has a bigger surface area than that (CuO-c, 3.4 m2/g) obtained by coprecipitation. The CuO samples and HKUST-1 were tested for low-temperature selective catalytic reduction (SCR) of NO with NH3 as reducing agent. The CuO-p catalyst derived from HKUST-1 exhibited the superior deNOx activity with respect to CuO-c. The further calcination at 600 °C under an N2 atmosphere is beneficial for improving the specific surface area and achieving an ideal SCR performance (TOF of 3.45 × 10−5 s−1 and ∼100% selectivity towards N2 at 270 °C). This work expands the potential applications of MOFs as catalysts.
中文翻译:
低温NH 3 -SCR工艺的HKUST-1镜腿衍生CuO催化剂的合成。
CuO催化剂是由HKUST-1太阳穴通过热解过程制备的,记为CuO- p。证实其具有八面体形状的形态是从HKUST-1继承而来的,但与通过共沉淀法制备的CuO- c基本上不同。而且,通过HKUST-1热解获得的CuO- p(15.4m 2 / g)具有比通过共沉淀获得的CuO- c(3.4m 2 / g)更大的表面积。测试了CuO样品和HKUST-1以NH 3为还原剂进行的NO的低温选择性催化还原(SCR)。源自HKUST-1的CuO- p催化剂表现出优异的de NO x关于CuO- c的活性。在N 2气氛下于600°C进一步煅烧有利于改善比表面积并实现理想的SCR性能(TOF为3.45×10 -5 s -1,在270°C下对N 2的选择性为〜100%) 。这项工作扩展了MOF作为催化剂的潜在应用。