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Sintering behaviour and microwave dielectric properties of BaAl2−2x(ZnSi)xSi2O8 ceramics
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2017-10-27 , DOI: 10.1016/j.jeurceramsoc.2017.10.053
Xiao-Qiang Song , Wen-Zhong Lu , Xiao-Chuan Wang , Xiao-Hong Wang , Gui-Fen Fan , Raz Muhammad , Wen Lei

BaAl2−2x(ZnSi)xSi2O8 (x = 0.2–1.0) ceramics were prepared using the conventional solid-state reaction method. The sintering behaviour, phase composition and microwave dielectric properties of the prepared compositions were then investigated. All compositions showed a single phase except for x = 0.8. By substituting (Zn0.5Si0.5)3+ for Al3+ ions, the optimal sintering temperatures of the compositions decreased from 1475 °C (x = 0) to 1000 °C (x = 0.8), which then slightly increased to 1100 °C (x = 1.0). Moreover, the phase stability of BaAl2Si2O8 was improved. A novel BaZnSi3O8 microwave dielectric ceramic was obtained at the sintering temperature of 1100 °C. This ceramic possesses good microwave dielectric properties with εr = 6.60, Q × f = 52401 GHz (at 15.4 GHz) and τf = −24.5 ppm/°C.



中文翻译:

BaAl 2−2 x(ZnSi)x Si 2 O 8陶瓷的烧结行为和微波介电性能

 使用传统的固态反应方法制备了BaAl 2−2 x(ZnSi)x Si 2 O 8x = 0.2–1.0)陶瓷。然后研究了制备的组合物的烧结性能,相组成和微波介电性能。除了x  = 0.8以外,所有组合物均显示出单相。通过用(Zn 0.5 Si 0.53+代替Al 3+离子,组合物的最佳烧结温度从1475°C(x  = 0)降低到1000°C(x  = 0.8),然后略微提高到1100° C(X = 1.0)。此外,提高了BaAl 2 Si 2 O 8的相稳定性。在1100℃的烧结温度下获得了新型的BaZnSi 3 O 8微波介电陶瓷。该陶瓷具有良好的介电性能与ε - [R  = 6.60,Q  ×  ˚F  = 52401千兆赫(15.4千兆赫)和τ ˚F  = -24.5 PPM /℃。

更新日期:2017-10-27
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