Cu-Induced [H6W12O42]6− polyoxometalate-based bimetallic cluster formation for renewable biomass inulin hydrolysis toward fructose production,Inorganic Chemistry Frontiers

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Cu-Induced [H6W12O42]6− polyoxometalate-based bimetallic cluster formation for renewable biomass inulin hydrolysis toward fructose production
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2017-10-12 00:00:00 , DOI: 10.1039/c7qi00516d
Yongdong Chen _{1,

2,

3,

4,

5} , Chaolei Zhang _{1,

2,

3,

4,

5} , Jiangwei Zhang _{5,

6,

7,

8,

9} , Zhongbin Ye _{1,

2,

3,

4} , Kai Zheng _{5,

6,

7,

8,

9} , Qihua Fang _{5,

6,

7,

8,

9} , Gao Li _{5,

6,

7,

8,

9}

Affiliation

Herein, a novel 3D open bimetallic Cu₃[H₆W₁₂O₄₂] cluster was designed as an effective solid acid catalyst for the hydrolysis of renewable biomass inulin by heterogeneous catalytic reaction towards fructose production with a high inulin conversion (∼100%) and fructose selectivity (∼90%) at low temperatures under aqueous condition with economic feasibility.

中文翻译：

铜诱导的[H ₆ W ₁₂ O ₄₂ ] ⁶⁻多金属氧酸盐基双金属簇形成，可再生生物质菊粉水解为果糖生产

本文中，设计了一种新型的3D开放式双金属Cu ₃ [H ₆ W ₁₂ O ₄₂ ]团簇，作为一种有效的固体酸催化剂，可通过非均相催化反应水解可再生生物质菊粉，从而生产具有高菊粉转化率（〜100％）的果糖。在含水条件下在低温下对果糖的选择性（约90％）具有经济可行性。

更新日期：2017-10-26

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