当前位置: X-MOL 学术ChemPlusChem › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Evaluation of Cyclooctatetraene-Based Aliphatic Polymers as Battery Materials: Synthesis, Electrochemical, and Thermal Characterization Supported by DFT Calculations
ChemPlusChem ( IF 3.4 ) Pub Date : 2017-10-19 03:45:35 , DOI: 10.1002/cplu.201700356
Martin E. Speer 1 , Christopher Sterzenbach 2 , Birgit Esser 1
Affiliation  

COT battery? Two aliphatic polymers, side-group-functionalized with cyclooctatetraene (COT) units, and four COT model compounds were synthesized and investigated towards their ability to serve as an electrode material in organic batteries (see figure). Although the model compounds showed promising electrochemical reversibility, the polymers suffered from thermal dimerization and cross-linking reactions between the COT units.

中文翻译:

评估基于环辛烯基的脂肪族聚合物作为电池材料:DFT计算支持的合成,电化学和热表征

COT电池?合成了两种用环辛酸酯(COT)单元进行侧基官能化的脂族聚合物和四种COT模型化合物,并研究了它们在有机电池中用作电极材料的能力(见图)。尽管模型化合物显示出令人满意的电化学可逆性,但聚合物却遭受了热二聚化和COT单元之间的交联反应的困扰。
更新日期:2017-10-19
down
wechat
bug