Department of Materials Science and Engineering; University of Toronto; 184 College Street Toronto Ontario M5S 3E4 Canada
Materials Chemistry and Nanochemistry Research Group; Solar Fuels Cluster; Department of Chemistry; University of Toronto; 80 St. George Street Toronto Ontario M5S 3H6 Canada
Department of Chemical Engineering and Applied Chemistry; University of Toronto; 200 College Street Toronto Ontario M5S 3E5 Canada
Department of Mechanical Engineering; Lassonde School of Engineering; York University; Toronto M3J 1P3 Canada
Department of Chemistry; Dalhousie University; 6274 Coburg Road, P.O. Box 15000 Halifax Nova Scotia B3H 4R2 Canada
Condensed Matter Physics and Materials Science Department; Brookhaven National Laboratory; Upton NY 11973 USA
Department of Physics; Temple University; Philadelphia PA 19122 USA
State Key Laboratory of Coal Conversion; Institute of Coal Chemistry; The Chinese Academy of Sciences; Taiyuan 030001 P. R. China
Zhejiang Key Laboratory of Drinking Water Safety and Distribution Technology; Zhejiang University; Hangzhou 310058 P. R. China
Department of Electrical and Computing Engineering; University of Toronto; 10 King's College Road Toronto Ontario M5S 3G4 Canada
The size dependence of the photothermal effect of palladium nanocrystals enables the selectivity of the solar powered heterogeneous catalytic hydrogenation of carbon dioxide to be finely tailored towards producing either carbon monoxide through the reverse water gas shift reaction, CO2 + H2 → CO + H2O, favored for small nanocrystals or to methane, via the Sabatier methanation reaction, CO2 + 4H2 → CH4 + 2H2O, preferred for larger nanocrystals. This is described by Geoffrey A. Ozin and co‐workers in article number 1700252.
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