The development of lower cost and higher performance phosphor materials for energy efficient lighting and other optoelectronic applications is both necessary and feasible. Luminescent metal–organic frameworks and coordination polymers (LMOFs and LCPs, respectively) are a class of materials that hold great promise for this application. Their luminescence is eminently tunable, and a myriad of structures with incredibly diverse properties have been reported, with emission wavelengths covering the entire visible spectrum, white light emission from a variety of mechanisms, and quantum yields approaching unity. This review will briefly describe the luminescence mechanisms commonly observed in these materials, discuss strategies for the rational design of LMOF/LCP phosphors, and present a number of representative examples of each mechanism and/or design strategy.

开发用于节能照明和其他光电应用的低成本和高性能的荧光粉材料既必要又可行。发光金属-有机骨架和配位聚合物（分别为LMOF和LCP）是一类具有广阔应用前景的材料。它们的发光非常可调，并且已经报道了无数种具有令人难以置信的特性的结构，发射波长覆盖了整个可见光谱，各种机制发出的白光发射，并且量子产率接近统一。本文将简要介绍这些材料中常见的发光机理，讨论LMOF / LCP荧光粉合理设计的策略，